On January 23, 2007 Adams debuted on the ECW brand, joining Kelly Kelly and Layla El in Extreme Exposé. This would become a weekly dance segment on the show. Adams made her in-ring WWE debut on the May 28, 2007 edition of Raw where she, along with several other WWE Divas from all three brands, competed in a Memorial Day Bikini Beach Blast Battle Royal, which was won by Michelle McCool.
Extreme Exposé acted as a weekly dance segment on the ECW show for months until The Miz was placed on the ECW brand in the annual WWE Draft Lottery, at which point all three ladies began actively pursuing him. Later, Kelly shifted her attentions to Balls Mahoney, to the amusement of The Miz and her Exposé sisters, who had been spending their time mocking his look which led her to turn into a heel character with Layla. Brooke, along with the other ECW Divas, as well as SmackDown and RAW Divas, would compete in a Number-One Contender's Battle Royal for Candice Michelle's WWE Women's Championship at SummerSlam, but Brooke got eliminated early on and with Kelly as the last ECW Diva standing, Beth Phoenix would ultimately win. Brooke's last match was a tri brand divas Halloween battle royal on the October 29, 2007 edition of Raw and even though she was eliminated early Kelly Kelly would eliminate Torrie Wilson to get the win for ECW.
Just a couple days later on November 1, 2007, Adams was released from her WWE contract.